Product ID:1,1,1-TRICHLOROETHANE DEGREASE COLD/VAPORS
MSDS Date:03/01/1986
FSC:6810
NIIN:00-476-5613
MSDS Number: BDZTL

ASHLAND CHEMICAL COMPANY

COLUMBUS, OH 43216-2219
US

Emergency Phone: 606-324-1133

Info Phone: 614-889-3333

Cage: 34897

ASHLAND CHEMICAL CO

2219 COLUMBUS, OH 43216-2219 US

Telephone: 614-790-3333/800-274-5263

Cage: 34897

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 90-95%

OSHA PEL 350 PPM/450 STEL

ACGIH TLV: 350 PPM/450STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PROPRIETARY INHIBITOR PACKAGE.(INCLUDE DIETHYLENE ETHER

1,4-DIOXANE (DIETHYLENE DIOXIDE) (SARA III)

CAS: 123-91-1

RTECS: JG8225000

OSHA PEL S, 100 PPM

ACGIH TLV: S, 25 PPM; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:IRRITATION OF
EYES,SKIN,RESPIRATORY OR G.I.TRACTS;CNS EFFECTS LIKE
HEADACHE,DIZZINESS,NAUSEA,VOMITING AND POSSIBLE
UNCONSCIOUSNESS;REDNESS OR BURNS OF EYES/SKIN
POSSIBLE.CHRONIC:DRYING OF SKIN,D EFATTING OR
DERMATITIS,LIVER,KIDNEY,LUNGS ABNORMALITIES OR HEART PROBLEM
Explanation of Carcinogenicity:THIS PRODUCT CONTAINS PROPRIETARY
INHIBITOR WHICH INCLUDES ( 1,4-DIOXANE)LISTED BY NTP AND IARC AS
ANIMAL CARCINOGEN.
Effects of Overexposure:EYES:SEVERE IRRITATION,REDNESS,TEARING,BLURRED
VISION;SKIN:DERMATITIS;INHALATION:RESPIRATORY
IRRITATION,DIZZINESS,WEAKNESS,FATIGUE,NAUSEA;INGESTION:NAUSEA,VOMIT
ING,DIARRHEA.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN, OR
RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE.

First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING.
GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER
FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION.
SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. IF
IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE
VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE
MEDICAL ATTENTION.

Flash Point:NONE
Lower Limits:7,5
Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL, OR WATER
FOG.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:NEVER USE WELDING OR CUTTING TORCH ON OR
NEAR DRUM AS PRODUCT CAN IGNITE EXPLOSIVELY.

Spill Release Procedures:USE PROPER PERSONAL PROTECTION;CONTAIN FREE
MATERIAL IF POSSIBLE;USE SUITABLE INERT ABSORBENT MATERIAL AND
RECOVER FOR PROPER DISPOSAL IN AN APPROVED CONTAINER.
Neutralizing Agent:NOT APPLICABLE.

Handling and Storage Precautions:USE ALL PRECAUTIONS AS PER LABEL.KEEP
THE CONTAINER CLOSED WHEN NOT IN USE.PROVIDE ADEQUATE VENTILATION.
Other Precautions:AVOID INHALATION OF VAPORS,SKIN KEYS CONTACT.USE
PROPER PERSONAL PROTECTIVE EQUIPMENT.

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR AS REQUIRED
IF ABOVE PEL/TLV OR SCBA IN AN ENCLOSED AREA.
Ventilation:LOCAL/GENERAL TO MAINTAIN PEL/TLV.
Protective Gloves:NEOPRENE, NITRILE, OR NATURAL RUBBER
Eye Protection:SAFETY GOGGLES WITH OPTIONAL FACE SHIELD
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER,WORK
CLOTHING AND APRON AS REQUIRED.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO
NOT BREATHE VAPORS OR MISTS.

HCC:T4
Boiling Pt:B.P. Text:190F,88C
Vapor Pres:100
Vapor Density:4.5
Spec Gravity:1.324
Evaporation Rate & Reference:2.6 (ETHYL ETHER=1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR LIQUID WITH MILD CHLOROFORM-LIKE ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH WATER,AL,MG,OPEN FLAME,WELDING ARCS.
Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND
OTHER UNIDENTIFIED COMPONENTS (HCL,SMALLL AMOUNT OF PHOSGENE OR
CL*2)

Waste Disposal Methods:CONSULT LOCAL AUTHORITIES.DISPOSAL MUST BE MADE
IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.